D*mble style Master Volumes aren't as intuitive as a typical one.
For maximum clean headroom on the clean channel, the idea is to set the Master Volume around 11-12 o'clock and the Volume between 12-3 o'clock.
If that doesn't work, it would't be a bad idea to double-check bias.
+1 !!!
Golden rule for 6L6 clean master volume amps is – volume on 11, master on 3 and find the sweet spot with bias between 30 – 35 ma (mv).
Than take volume to 12 or 1 o’clock and master on 11-12.
Set overdrive to taste and it will be as smooth as silk.
Or do whatever pleases you.